Study Of Titanium Molybdophosphate (tmp) Lead V Anadophospha Te (l Vp) And Zirconium Vanadophosphate (zrvp) Supported Catalysis By Some Transition Metal Ions In The Conversion Of Cyclohexanol And Cyclohexene

TMP, L VP and ZrVP as an inorganic material SUppOit for transition metal catalysts are usedrnin this project. The basic parameters such as: elemental analysis, IR spectrum, hydrogen ionrnexchange capacity, pH titration and moisture contents for each exchanger have been studied.rnCatalytic applications of ZrVP, L VP and TMP as a support by loading CrJ+ on each, andrnCu'+ and Fe3+ on ZrVP, have been studied in dehydration of cyclohexanol and in the hydrationrnof cyclohexene. From the GC analyses the suppOited catalysts were found to be efficient inrndehydrating cyclohexanol but not for the hydration of cyclohexene. The major product identifiedrnby retention time coincidence test and peak enhancement teclmique was cyclohexene. In thisrnwork the most efficient being ZrVP and the percentage composition of the product obtained arern48% for ZrVPlFe3+, 35% for ZrVP/Cr'+ and 29% for ZrVP/C112+

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