In this work five N-arenesulphonyl-benzimidoyl-N’- thiourea derivatives werernsynthesized from intermediate of N-arenesulphonyl-benzimidoyl- rodanide (3) byrnreacting with different bascity of amines. Out of these derivatives compound 4,5 and 6rnwere synthesized by reacting rodanide (3) with aromatic amines (aniline and p-methylrnaniline) and the rest of the two compounds ,compound 7 and 8, were synthesized byrnreacting of rodanide (3) with ammonia solution and glycine. Their structures wererndetermined by using NMR and IR spectroscopic method.rnII