Some Aspects Of The Organic Chemistry Of Sulphur

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n t h i s report, the Wmgerodt-Kindler reaction hasbeen reviewed, and a. variant of the reaction has "beendeveloped.In t h i s , good yields of thioamides have been obtained

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"by reaction of aldehydes or ketones with s a l t s of v o l a t i leamines and anhydrous sodium acetate in dimethylformamideat moderate temperatures, thus avoiding the conventionaluse of pressure vessels and high temperatures.The thioamides with alkyl halides give S-alkylquaternarys a l t s , which have been reacted with variousnucleophilic reagents: hydrazine hydrate, sodium borohydrideand diazomethane: giving interesting products.

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Project ID TH6065

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Some Aspects Of The Organic Chemistry Of Sulphur

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